Effect of Hydrogenation Process in Several Palm Oil Derivatives on Its Application as Edible Wax to Replace Paraffin in Wax Applications

Ahmad Husni Lubis (1), Ifa Puspasari (2), Diana (3)
(1) Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Islam Indonesia, Yogyakarta, Indonesia
(2) Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Islam Indonesia, Yogyakarta, Indonesia
(3) Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Islam Indonesia, Yogyakarta, Indonesia
Fulltext View | Download
How to cite (AJARCDE) :
Ahmad Husni Lubis, Puspasari, I., & Diana. (2025). Effect of Hydrogenation Process in Several Palm Oil Derivatives on Its Application as Edible Wax to Replace Paraffin in Wax Applications. AJARCDE (Asian Journal of Applied Research for Community Development and Empowerment), 9(2), 15–21. https://doi.org/10.29165/ajarcde.v9i2.640

Wax is mostly produced using paraffin as its formulation, but nowadays, for food safety and environmental reasons, edible wax has become highly possible as a substitute. The hydrogenation process has been carried out on several derivatives of palm oil, namely refined palm stearine (RPS), refined palm oil (RPO), palm soft stearin (SST), Palm mid-olein (MOL), and Palm Mid Fraction (PMF) through 3 types of hydrogenation processes, namely: (1) complete hydrogenation with a target iodine value <1, (2) partial hydrogenation with limiting hydrogen gas consumption, and (3) partial hydrogenation with limiting reaction time. The hydrogenated products were characterized and compared to commercial paraffin and wax according to several parameters such as Solid Fat Content, crystallization rate, melting rate, melting point, smoke point, and flash point. Furthermore, we applied the hydrogenated products to both the wax products and a mixture of hydrogenated and paraffin products. The wax produced was then evaluated based on several parameters, such as hardness, combustion flame, melting diameter, and combustion time. The findings concluded that all hydrogenated products can be used as raw materials for wax, either their self or hydrogenated and paraffin formulation products. Waxes made from Refined Hydrogenated Palm Stearin (RHPS)-1 and Refined Hydrogenated Palm Oil (RHPO)-1 are the hardest wax in terms of texture. In contrast, in the case of flame, the waxes made from hydrogenated products formulated with paraffin and paraffin itself have brighter flame than the others and Refined Hydrogenated Soft Stearin (RHSST)-1 and Refined Hydrogenated Palm Mid Fraction (RHPMF)-1 waxes are the waxes that burn the longest. Each wax has certain characteristics that can be related to the hydrogenated product used.


Contribution to Sustainable Development Goals (SDGs):
SDG 3: Good Health and Well-being
SDG 9: Industry, Innovation, and Infrastructure
SDG 12: Responsible Consumption and Production
SDG 13: Climate Action

[1] Togas, C., Berhimpon, S., Montolalu, R. I., Dien, H. A., & Mentang, F. (2017). Karakteristik Fisik Edible Film Komposit Karaginan Dan Lilin Lebah Menggunakan Proses Nanoemulsi. Jurnal Pengolahan Hasil Perikanan Indonesia, 20, 468–477.

[2] Agustina, M. (2021). Formulasi dan Uji Efektifitas Sediaan Lilin Aroma Terapi (Antinyamuk) Dari Minyak Cengkeh (Syzygium Aromaticum Linn). Karya Tulis Ilmiah, hlm. 10.

[3] Murphy, T. A., & Thomas, G. J. (2019). Wax Compositions and The Effect Of Metals On Burn Rates (WO 2014). World Intellectual Property Organization. https://lens.org/058-093-635-921-541

[4] Parmar, B. J., Dutta, P. S. M., & Thakore, P. S. B. (2016). Process Design for Hydrogenation of Palm Oil. April, 1–4.

[5] Holdewel, M., Bhaggan, K., & Man, H. K. (2019). Palm Oil Product For use as a Wax Wax and Process (EP 3 247 780 B1). European Patent Spesification.

[6] Murphy, T. A., Doucette, M. K., House, N. C., & Richards, M. L. (2003). Tracylglycerol-Based Alternative To Paraffin Wax (US 6,645,261 B2). United States Patent.

[7] Rahayu, A. I., Sasmita, G. S., Setiani, I. A., Arfiyani, I. A., & Ainun, Y. (2020). Formulasi dan Uji Evaluasi Fisik Sediaan Lilin Aromaterapi Dari Kombinasi Minyak Atsiri Sereh ( Cymbopogon citratus ) dan Minyak Atsiri Jeruk ( Citrus aurantifolia ). 2–5.

[8] Rusli, N., & Rerung, Y. W. R. (2018). Formulasi Sediaan Lilin Aromaterapi Sebagai Anti Nyamuk Dari Minyak Atsiri Daun Nilam (Pogostemon cablin Benth) Kombinasi Minyak Atsiri Buah Jeruk Nipis (Citrus aurantifolia Swingle). Jurnal Mandala Pharmacon Indonesia, 4(1), 68–73. https://doi.org/10.35311/jmpi.v4i1.26

[9] Pancarani, L., Amananti, W., & Santoso, J. (2020). Formulasi dan evaluasi sediaan ginger scented wax sebagai aroma terapi. Jurnal Farmasi, 7(1), 1–7.

[10] Rahardja, I. B., Mahfud, A., Dermawan, Y., & ... (2019). Pelatihan Pembuatan Lilin Untuk Penerangan Rumah Tangga Menggunakan Bahan Dasar Crude Palm Oil (CPO). Seminar Nasional Pengabdian Masyarakat LPPM UMJ, 3(September), 1–4.

[11] Agogué, M. C., Loisel, C., Gonçalves, O., Legrand, J., Saint-Jalmes, S., & Arhaliass, A. (2022). Multi-scale study of the structuration of wax blends with a high content of vegetable fats to replace paraffins: Effect of 12-hydroxystearic acid content. JAOCS, Journal of the American Oil Chemists’ Society, 99(12), 1137–1150. https://doi.org/10.1002/aocs.12625

[12] Hamins, A., Bundy, M., & Dillon, S. E. (2005). Characterization of wax flames. Journal of Fire Protection Engineering, 15(4), 265–285. https://doi.org/10.1177/1042391505053163

Downloads

Download data is not yet available.